The characteristics of copper containing SBA-15 prepared by impregnation and pH adjustment methods and their activities for N2O decomposition

Mohd Husin, Mohd Haizal and Dewayanto, Nugroho and Nordin, Mohd Ridzuan and Jinli, Li (2015) The characteristics of copper containing SBA-15 prepared by impregnation and pH adjustment methods and their activities for N2O decomposition. Advances in Environmental Biology, 9 (6). pp. 6-14. ISSN 1995-0756

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Abstract

Two types of Cu-SBA-15 catalysts were successfully prepared by impregnation and by pH adjustment methods. All synthesized materials have been characterized by XRD, Nitrogen adsorption–desorption, and TEM. After the impregnation of copper, the unit-cell, specific surface area and pore volume of SBA-15 were found to decrease, while the formation of CuO deposited on the framework was detected. On the contrary, the catalyst prepared by pH modification method indicated the increase of unit-cell, surface area, pore volume, and wall thickness after the incorporation of the copper ions on SBA-15 and copper atoms were substituted into the framework of the SBA-15. Series of N2O decomposition experiments were carried out using the catalysts. Cu/SBA-15 samples prepared by pH adjustment method showed higher catalytic activity thanCu-SBA-15 samples prepared by impregnation method.

Item Type: Article
Uncontrolled Keywords: Cu-SBA-15, Impregnation, pH modification, Characteristics, N2O decomposition
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Mechanical Engineering > Department of Automotive
Depositing User: Mohd Haizal Mohd Husin
Date Deposited: 30 Mar 2015 06:59
Last Modified: 04 Jul 2023 11:03
URI: http://eprints.utem.edu.my/id/eprint/14371
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