Abd Razak, Jeefferie and Haji Ahmad , Sahrim and Ratnam, Chantara Thevy and Mahamood, Mazlin Aida and Mohamad, Noraiham (2015) Effects of EPDM-g-MAH compatibilizer and internal mixer processing parameters on the properties of NR/EPDM blends: an analysis using response surface methodology. Journal of Applied Polymer Science, 132 (27). pp. 1-15. ISSN 1097-4628 (In Press)
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Abstract
ABSTRACT: This study evaluates the effects of ethylene-propylene-diene-monomer grafted maleic anhydride (EPDM-g-MAH) and internal mixer melt compounding processing parameters on the properties of natural rubber/ethylene-propylene-diene rubber (NR/ EPDM) blends. Using Response Surface Methodology (RSM) of 25 two-level fractional factorial, we studied the effects of NR/EPDM ratio, mixing temperature, Banbury rotor speed, mixing period, and EPDM-g-MAH contents in NR/EPDM blends. The study found that the presence of EPDM-g-MAH in NR/EPDM blends had a predominant role as a compatibilizing agent, which affected the processability and properties of the final material. We also determined the model fitting with constant determination, R2 of 99.60% for tensile strength (TS) response with a suggested combination of mixing process input parameters. The reproducibility of the proposed mixing strategy was then confirmed through model validation with a minor deviation at 12.303% and higher desirability of 0.960. This study is essential in providing a process design reference for NR/EPDM blends preparation by melt-blending and the role of a compatibilizer from the systematic Design of Experiment (DOE) approach. The experimental findings were further supported with swelling and cross-link density measurements, differential scanning calorimetry analysis, and observation of fracture morphology using a scanning electron microscope. VC 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42199.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | compatibilization; crosslinking; elastomers; rubber |
| Subjects: | T Technology > TS Manufactures Q Science > QD Chemistry Q Science > QC Physics |
| Divisions: | Faculty of Manufacturing Engineering > Department of Engineering Materials |
| Depositing User: | En. Jeefferie Abd Razak |
| Date Deposited: | 21 May 2015 09:12 |
| Last Modified: | 28 May 2015 04:38 |
| URI: | http://eprints.utem.edu.my/id/eprint/14472 |
| Statistic Details: | View Download Statistic |
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